Search results for "CRYSTALLINE STRUCTURE"

showing 3 items of 3 documents

Premature aging in bone of fish from a highly polluted marine area

2015

Fish species have attracted considerable interest in studies assessing biological responses to environmental contaminants. In this study, the attention has been focussed on fishbone of selected fish species from a highly polluted marine area, Augusta Bay (Italy, Central Mediterranean) to evaluate if toxicant elements had an effect on the mineralogical structure of bones, although macroscopic deformations were not evident. In particular, an attempt was made to evaluate if bone mineral features, such as crystallinity, mineral maturity and carbonate/phosphate mineral content, determined by XR-Diffraction and FT-IR Spectroscopy, suffered negative effects due to trace element levels in fishbone,…

ChromiumMediterranean climatePremature agingAugusta Bay (Italy)XRDMineralogyAquatic ScienceOceanographyBone and Boneschemistry.chemical_compoundCalcification PhysiologicX-Ray DiffractionSpectroscopy Fourier Transform InfraredAnimalsBone mineralMaturity (geology)Body WeightWater PollutionFishesTrace elementCrystalline structure fishboneReproducibility of ResultsAging PrematureMercuryContaminationPollutionHydroxylapatiteFT-IRItalychemistryEnvironmental chemistryTrace elementEnvironmental scienceCarbonateBay
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Structural and Mössbauer study of (Sb0.70Te0.30)100-x Snx alloys with x = 0, 2.5, 5.0 and 7.5

2019

(Sb 0.70 Te 0.30 ) 100-x Sn x alloys (with x = 0, 2.5, 5.0 and 7.5 at. %)have been synthesized and characterized in order to determine the crystalline structure and properties of materials obtained upon solidification and to extract information about the location of the Sn atom in the Sb-Te matrix. Powder X-ray diffraction (XRD)has been used to determine the crystalline structure, whereas Mössbauer spectroscopy has been utilized to determine the localization and the local structure of the Sn atom in the Sb-Te matrix through the hyperfine interactions of the 119 Sn probe with its environment. We found that Sb 70 Te 30 crystallizes in a trigonal structure belonging to P-3m1 space group, while…

Materials scienceCRYSTALLINE STRUCTUREchemistry.chemical_element02 engineering and technologyCrystal structure010402 general chemistry01 natural sciencesDFTMössbauer spectroscopyAtomMaterials ChemistryHyperfine structureCHALCOGENIDE ALLOYSMechanical EngineeringDopingMetals and Alloys021001 nanoscience & nanotechnology0104 chemical sciencesCrystallographySN MÖSSBAUER SPECTROSCOPYchemistry//purl.org/becyt/ford/2 [https]Mechanics of MaterialsDensity functional theory0210 nano-technologyGround stateTin//purl.org/becyt/ford/2.5 [https]
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Initial stages of metal oxides thin films growth by MOCVD: physicochemical characterisation of the film/substrate interface

2006

The initial stages of Metalorganic Chemical Vapour Deposition (MOCVD) of TiO2 thin films on Si(100) were studied in situ by surface analyses (XPS, ARXPS, AES). An original experimental set-up was built for this purpose and developed. Information obtained from these in situ experiments was completed by ex situ characterisations (HRTEM, SIMS, GIXRD...).The formation of an interfacial SiOy<2 layer resulting of the interaction of the precursor Ti(OCH(CH3)2)4 with the substrate takes place before the formation of stoichiometric TiO2 and leads to the presence of carbon at the interface. At the deposition temperature, 675 °C, silicon diffusion within the TiO2 external layer was also revealed. Conc…

[CHIM.MATE] Chemical Sciences/Material chemistryinterfacial reactivityin situ surface analysisARXPScrystalline structure[ CHIM.MATE ] Chemical Sciences/Material chemistryMOCVDTEMXPSstructure cristallineMETréactivité interfacialeanalyse de surfaces in situTiO2/Si
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